PBT properties are derived from REACH registered substances dossiers. The light blue bar illustrates the percentage of matching substance classifications provided by manufacturers and importers in CLP notifications. Processable data for summary is prioritised by test species (see list below) and subsequently further prioritised by the dose descriptor. The Agency thus cannot guarantee the correctness of the information displayed. Solubility in organic solvents / fat solubility. Contact with acids liberates very toxic gas. Processable data is prioritised by the toxicity descriptor type (see list below) and subsequently further prioritised by duration (longer prioritised over shorter). This section summarises the values related to toxicity to aquatic algae and cyanobacteria from all registered dossiers for the substance. Brief Profile - Last updated: 01/12/2020 Print. Please be aware that as additional data is submitted to ECHA, the brief profile will also be updated to reflect the new situation. 333-20-0 This main layer contains sublayers for the chemical formula, atom connections and hydrogen atoms. Hazard pictogram GHS07: exclamation mark GHS05: corrosion Hazard statements H302+H312+H332: Harmful if swallowed, in contact with skin or if inhaled. HARMFUL IF SWALLOWED OR INHALED. Solubility in mg/100g standard fat at 20°C provides substance information on the substance solubility in standard fat in milligram per 100 gram at a temperature of 20°C. This section summarises the dissociating values from all registered dossiers for the substance. SMILES is the acronym for Simplified Molecular Input Line Entry Specification, a chemical notation system used to represent a molecular structure by a linear string of symbols. May cause eye irritation. This section summarises the values related to short–term toxicity to fish from all registered dossiers for the substance. Though the Agency aims to include as many studies as possible in the Brief Profile endpoint study results/summaries, those studies which do not fit the format or miss crucial information (such as measurement conditions) cannot be processed and therefore will not be included on this page. If so, the data provided is not processed in the Brief Profile. The bars indicate the number of matching classifications, i.e. Data is generally standardised and displayed in milligram per kilo soil (dry weight). ECHA’s Guidance Chapter R.12: Use Descriptor system of ECHA’s Guidance on information requirements and chemical safety assessment, ECHA guidance chapter R.12: Use Descriptor system of ECHA Guidance on information requirements and chemical safety assessment, Guidance on the safe use of the substance, Endocrine disrupter testing in aquatic vertebrates – in vivo, Active/Inactive (pending). EC10 / LC10 or NOEC for marine water invertebrates provides substance information on the substance’s effect concentration/lethal concentration for 10% of the tested marine water invertebrates or the no observed effect concentration for marine water invertebrates. Oxidising. Duration of exposure, concentration of … This substance is used by professional workers (widespread uses), in formulation or re-packing, at industrial sites and in manufacturing. 333-20-0 Potassium Thiocyanate <1.0 % 206-370-1 Hazard Symbols: XN Risk Phrases: 21/22 32 Section 3 - Hazards Identification EMERGENCY OVERVIEW Appearance: clear, colorless liquid. Nulla pulvinar vitae nunc vitae sagittis. Processable data is prioritised by the toxicity descriptor type (see list below) and subsequently further prioritised by duration (in hours, longer prioritised over shorter). This section provides information on the recommended measures to minimise or prevent adverse effects resulting from exposure to a hazardous product, or improper storage or handling of a hazardous product. Release to the environment of this substance can occur from industrial use: manufacturing of the substance. Registrants can provide data for one or more of the following picklist options: Note: Registrants can also select ‘other’ as the solvent. Data is generally displayed in milligrams per kilogram in the case of soil (dry/wet weight), or gram per hectare. level’ as the dose descriptor. Values are generally displayed in milligram per kilo soil (dry weight). For this endpoint registrants do not provide study result data. Displayed are the RANGES of min – max of the PRIORITISED value(s) within the five highest priority groupings of provided data. Target Organs: Heart, brain. Note: Registrants can also select ‘BMD’, ‘BMC’, ‘dose level’ and ‘conc. Displayed is the most conservative of the prioritised value(s). Phototransformation in soil provides substance information on the substance’s phototransformation in soil in seconds/minutes/hours/days/weeks/months/years. Hazard for terrestrial organisms provides information on the substance’s hazard assessment conclusion related to terrestrial organisms/soil. Note: If a temperature value is not provided by the registrant, the information on half-life in water will not be processed for the Brief Profiles. If swallowed: call a poison center or doctor/physician if you feel unwell. Autoflammability / Self-ignition at 101 325 Pa provides substance information on the substance’s self-ignition temperature in °C at a pressure of 101 325 Pa. The availability of additional data beyond the five results displayed is indicated by (…). Values are displayed in milligram per litre. GHS Hazard Statements: H300: Fatal if swallowed [Danger Acute toxicity, oral] H312: Harmful in contact with skin [Warning Acute toxicity, dermal] H330: Fatal if inhaled [Danger Acute toxicity, inhalation] H373 **: Causes damage to organs through prolonged or repeated exposure [Warning Specific target organ toxicity, repeated exposure] This section provides an overview of the type of study records behind the presented results and – if applicable - data-waving justifications. The substance identifiers – if available and not claimed confidential – displayed in the ’Substance identity’ section of the Brief Profile are: In addition, information on the type of substance, origin, number and type of registered compositions and other places where the substance is listed are displayed in this section. Applicant’s summary and conclusion – Interpretation of results provides information on the substance’s biodegradation properties in water and can be registered by the registrants by one or more of the following picklist options: Note: Registrants can also select ‘other’ as picklist option for describing the biodegradation values of the substance in water. LC50 for marine water invertebrates provides substance information on the substance’s lethal concentration for 50% of the marine water invertebrates in the test, displayed in milligram per litre. : 333-20-0 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratorychemicals, Industrial & for professional use only. Articles of Potassium thiocyanate are included as well. Oxidation reduction potential in mV at 20°C provides substance information on the substance’s oxidation reduction measured in millivolts at a temperature of 20°C. Readily biodegradable but failing the 10-day window. 1.6), oxidising: maximum burning rate equal or higher than reference mixture, oxidising: vigorous reaction in preliminary test.   Prolonged absorption of thiocyanates may produce various skin eruptions, running nose, dizziness, cramps, nausea and vomiting. This substance has not been registered under the REACH Regulation, therefore as yet ECHA has not received any data about this substance from registration dossiers. Testing. Component Common Name / Synonyms CAS# Chemical Formula % by Weight Potassium Thiocyanate Potassium Thiocyanide 333-20-0 KSCN ≥ 98.5 . Displayed is the most conservative of the prioritised value(s).   Health Hazard Data of the Chemical. Therefore, data has to fit the format and aggregation logic that is used for the Brief Profile. 'IUPAC name' is the generic field by which substance names are provided in various data submission tools. PIC administers the import and export of certain hazardous chemicals and places obligations on companies who wish to export these chemicals to non-EU countries. Biodegradation in water - screening tests, Biodegradation in water & sediment - simulation tests. Release to the environment of this substance can occur from industrial use: formulation of mixtures.   The CLP regulatory processes identified for the Brief Profile are: The BPR (528/2012) entered into force on 1 September 2013. The IUPAC nomenclature is a systematic way of naming chemical substances, both organic and inorganic. 1 Reagent Lane This section displays all the public names and other identifiers available in ECHA's databases for the substance. More information about classification and labelling can be found in the Regulations section of ECHA website. Applicant’s summary and conclusion – Interpretation of results. The POPs regulatory processes identified for the Brief Profile are: Classification, Labelling and Packaging (CLP)The CLP Regulation (1272/2008) entered into force on 20 January 2009. This section summarises the partition coefficient values from all registered dossiers for the substance. Data is generally displayed in milligrams per kilogram in the case of soil (dry/wet weight), or gram per hectare. Section 3: Composition / Information on Ingredients Potassium Thiocyanate (333-20-0), <1%. COMPOSITION AND INFORMATION ON INGREDIENTS. Additives are the constituents which have been intentionally added during the manufacturing process to stabilise the substance. The total number of non-confidential registered compositions submitted in REACH dossiers are displayed here. Values are generally displayed in milligram per litre. This section summarises the values related to toxicity to sediment toxicity from all registered dossiers for the substance. Study results are not processed for carcinogenicity in the context of Brief Profiles due to the use of complex field(s) to report the information, which cannot be easily summarised by an automatic algorithm. The Agency thus cannot guarantee the correctness of the information displayed. 1.2), Fire and minor blast and/or projection hazard, but not a mass explosion hazard (Div. The quality and correctness of the information remains the responsibility of the data submitter. Note: If the measurement condition (percentage of organic carbon) is not provided by the registrant for adsorption coefficient Kd, the data provided is not processed for the Brief Profile. Applicant’s summary and conclusion – Interpretation of results. The Brief Profile summarizes the non-confidential data on substances as it is held in the databases of the European Chemicals Agency (ECHA), including data provided by third parties. Note: Results without a concentration value are not processed for the Brief Profile. If more than one result is available per endpoint, the range of results (min-max, RANGE method) will be presented. Displayed are the RANGES of min – max of the PRIORITISED value(s) within the five highest priority groupings of provided data. If there is more than one result with the same value, data is further prioritised by test type and endpoint conclusion. This section provides information on the derived no- or minimal effect level (DN(M)EL), the level of exposure above which a human should not be exposed to a substance. InChI is an abbreviated name for IUPAC International Chemical Identifier, a chemical identifier developed and supported by the InChI Trust. The quality and correctness of the information remains the responsibility of the data submitter. Additionally, if registrants select ‘other’ as a unit of measure for pressure, the measurement conditions (and therefore the study results) cannot be processed in the Brief Profile. See information under ‘Study results oral’. * Prolonged exposure to Potassium fumes can cause sores of the inner nose. If on skin: wash with soap and water. The derived no- or minimum effect level (DN(M)EL) is the level of exposure above which a human should not be exposed to a substance.   Thirdly the display of data is prioritised by units. For substance’s physical state at 20°C and 1 013 hPa, registrants can classify their substance as: For substance’s form, registrants can classify their substance as: For substance’s odour, registrants can classify their substance as: For substance’s type, registrants can classify their substance as: Summary data is collected from the endpoint summary(ies) provided by registrants of REACH dossiers. For general information about any of the different regulations which currently fall under ECHA’s mandate please see the links below. Product name : Potassium thiocyanate solution Product Number : 35194 Brand : Fluka 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Manufacture of substances 1.3 Details of the supplier of the safety data sheet Company : Sigma-Aldrich 3050 Spruce Street If more than one numerical result is available per endpoint, the range of results (min-max) and range of experimental conditions will be presented (RANGE method).Relative density provides substance information on the relatively density (measurement units are not processed for relative density) at a temperature measured in Celsius (°C). Regulatory process names gives the names under which the substance appears in ECHA's regulatory processes and lists. Section 4 - First Aid Measures This section provides an overview of the type of study records behind the presented results and – if applicable - data waving justifications. Registration – indicated if there is at least one dossier registered and disseminated for the substance, how many non-confidential registrations are active and/or inactive and the type of submissions (joint and/or individual). PubChem Substance ID 24898354. See the official IUPAC website for more information on the International Union of Pure and Applied Chemistry. The availability of additional data beyond the five results displayed is indicated by (…). For accuracy reasons, substance manufacturers and imports have the responsibility to consult official sources, e.g. Please note that when more than one summary is provided, DN(M)EL values may refer to constituents of the substance and not to the substance as a whole. D) Shelf life is probably several months, but it is advisable to make it up freshly. 3. If additional information derived from classification and labelling (C&L) notifications to ECHA under the CLP Regulation exists, this will be displayed below the information derived from harmonised classification and labelling and REACH registrations. Oral route provides substance information on the substance’s acute toxicity via the oral route. Potassium Thiocyanate, 0.1M Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com CAS 333-20-0 Potassium Thiocyanate, ACS 0.9718 % CAS 7732-18-5 Deionized Water 99.028 % Percentages are by weight SECTION 4 : First aid measures Description of first aid measures After inhalation: Remove to fresh air. Therefore this does not constitute official and legally binding information. Please see the registered dossiers for substance information for the following endpoints: The ’Substance identity’ section links substance identification information from all databases that are maintained by ECHA. Values are generally displayed in milligram per kilo soil (dry weight). The information has not been reviewed or verified by ECHA or any other authority. Data generally displayed in milligrams per kilogram bodyweight per day. Product: Potassium Thiocyanate Revision Date: 07/17/2013 5/7 . Precautions for using this substance have been recommended by its registrants under REACH, as follows: When handling this substance: use only outdoors or in a well-ventilated area; do not eat, drink or smoke when using this product; avoid release to the environment; wash parts of the body (as specified by manufacturer/supplier)in contact with substance thoroughly after handling; wear protective gloves and/or clothing, and eye and/or face protection as specified by manufacturer/supplier; avoid breathing the dust, fume, gas, mist, vapours or spray. ECHA has no public registered data on the use of this substance in activities or processes at the workplace. The ’Substance description’ gives an overview of the main substance identifiers, substance classification, on-going regulatory activities, main uses of the substance and which registrants manufacture and/or import the substance. Degradation rate constant with OH radicals provides substance information on the substance’s degradation rate constant with OH Radicals as a reaction type in cm3molecule-1s-1, cm3molecule-1d-1, m3molecule-1s-1 or m3molecule-1d-1. Product name Potassium thiocyanate for analysis EMSURE® ACS,ISO,Reag. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Product name : Potassium Thiocyanate CAS-No.   Inherently biodegradable, fulfilling specific criteria; Inherently biodegradable, not fulfilling specific criteria, Under test conditions no biodegradation observed. For accuracy reasons, substance manufacturers and importers are responsible for consulting official sources. If more than one type of substance is registered, both types will be displayed. If a threshold is derived, the type of hazard assessment conclusion is displayed and the registered threshold is reported in (nano/micro/milli)gram per cubic metre. 3. 3. The data presented in these sections has been cleaned to remove names of one character or less, or names which consist solely of punctuation or numerical characters. If only waived data is available for the substance, following justifications for data-waiving can be displayed in the Brief Profile: Some endpoints are not included in the Brief Profile due to the use of free text and/or complex field(s) in the reporting of information, which cannot be easily summarised by an automatic algorithm. The Brief Profile summarises the non-confidential data on substances as it is held in the databases of the European Chemical Agency (ECHA), including data provided by third parties. 1.3), Very insensitive substances with mass explosion hazard (Div. List of substances subject to the POPs Regulation - Indicates if the substance is included in the POPs Regulation. This section summarises the Ecotoxicological information provided from all registered dossiers for the substance. If more than one IUPAC name is available from REACH registered dossiers, all IUPAC names are displayed in ‘Other names’ section of the Brief Profile. This section summarises the values related to toxicity to aquatic plants (other than algae) from all registered dossiers for the substance. Skin sensitisation provides substance information on the substance’s sensitisation effect on the skin. Processable data is prioritised by the toxicity descriptor type (see list below) and subsequently further prioritised by duration (longer prioritised over shorter).   Inhalation: Product name : Potassium Thiocyanate CAS-No. 1.5), Extremely insensitive which do not have a mass explosion hazard (Div. Displayed are the RANGES of min – max of the PRIORITISED value(s) within the five highest priority groupings of provided data. For this endpoint registrants do not provide summary data. Sigma-Aldrich offers a number of Potassium thiocyanate products. Potassium thiocyanate CAS 333-20-0 for analysis EMSURE® ACS,ISO,Reag. Ingestion: May cause psychosis, vomiting, disorientation, weakness, low blood pressure, convulsions and death which may be delayed. 1.3 Details of the supplier of the safety data sheet Company : Central Drug House (P) Ltd 7/28 Vardaan House New Delhi-10002 INDIA Short-term EC50 or LC50 for soil dwelling arthropods provides substance information on the substance’s effect concentration or lethal concentration (short term) for 50% of the soil dwelling arthropods in the test, generally displayed in milligram per kilo soil (dry weight). Potassium Thiocyanate is an inorganic salt. H dimensionless volumetric basis provides substance information on the substance’s Henry’s Law Constant in dimensionless volumetric basis at a temperature measured in °C and a pressure measured in Pascal. If information on guidance on safe use is available in REACH registered dossiers, a link is displayed. Authorisation list (Annex XIV) – indicates if the substance is included in the Authorisation List. Synthesis. Long-term EC10 or LC10 or NOEC for birds provides substance information on the substance’s effect concentration or lethal concentration (long term) for 10% of the birds in the test, or the no observed effect concentration for birds. Pre-registration allows companies to continue manufacturing and importing their. This section summarises the values related to toxicity to (terrestrial) arthropods from all registered dossiers for the substance. This section summarises the water solubility values from all registered dossiers for the substance. Registrants can register their substance explosiveness as: This section summarises the oxidising values from all registered dossiers for the substance. The percentage is based on the count of values provided. Values are presented in (nano/ micro/milli)gram per litre and/or (nano/ micro/milli)molar per litre. Thirdly the display of data is prioritised by units . The CAS number is the substance numerical identifier assigned by the Chemical Abstract Service, a division of the American Chemical Society, to substances registered in the CAS registry database. Displayed are the RANGES of min – max of the PRIORITISED value(s) within the five highest priority groupings of provided data. Dissipation Half-life of parent compound provides substance information on the substance’s dissipation half-life for the parent compound per second/minute/hour/day/week/month/year. 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